Let $K$ be an abstract simplicial complex on the vertex set $[n] = \{1\dots,n\}$. We represent dimension $i$ faces of $K$ as lexicographically ordered cardinality $i+1$ subsets $\{l_0 < \dots < l_i\}$ of $[n]$. We further let $C_i$ be the free abelian group on the set of $i$-dimensional faces of $K$.
By these conventions the differential from the free abelian group of $K$'s dimension $i$ faces to the free abelian group of $K$'s dimension $i-1$ faces sends each $\{l_0 < \dots < l_i\}$ to the signed sum of all lexicographically ordered sets $\{l_0 < \dots < l_i\} \backslash \{l_j\}$ as $j$ ranges from $0$ to $i$.
Here, the sign in front of $\{l_0 < \dots < l_i\} \backslash \{l_j\}$ is $(-1)^j$.
Using the constructors simplicialChainComplex and reducedSimplicialChainComplex respectively, non-reduced and reduced simplicial chain complexes can be constructed in the following way.
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The source of this document is in AbstractSimplicialComplexes.m2:526:0.